2-tert-Butyl-4-methyl-6-(1,3-oxazinan-1-ylmethyl)phenol
نویسندگان
چکیده
منابع مشابه
2-tert-Butyl-4-methyl-6-(1,3-oxazinan-1-ylmethyl)phenol
The title compound, C(16)H(25)NO(2), which was synthesized by a Mannich reaction route, is a rare example of an organic compound containing the six-membered oxazine ring. The ring adopts a chair conformation and the N atom is pyramidal. The N atom serves as a hydrogen-bond acceptor to the phenolic OH group.
متن کاملtert-Butyl 6-methyl-2-oxo-4-[4-(trifluoromethoxy)anilino]cyclohex-3-ene-1-carboxylate
In the title compound, C(19)H(22)F(3)NO(4), the dihedral angle between the benzene ring and the conjugated part of the enaminone ring is 42.5 (1)°. The ester substituent makes a dihedral angle of 81.3 (2)° with this latter moiety. The crystal structure is held together by strong N-H⋯O and weak C-H⋯O inter-molecular inter-actions. The enaminone ring is disordered over two orientations with relat...
متن کامل2-tert-Butyl-6-(cyclohexyliminomethyl)-4-methoxyphenol
The asymmetric unit of the title Schiff base compound, C(18)H(27)NO(2), contains two independent mol-ecules in which the C=N bond lengths are 1.278 (2) and 1.280 (2) Å and the cyclo-hexane rings adopt chair conformations. Intra-molecular O-H⋯N hydrogen bonding between hy-droxy and imine groups and weak C-H⋯O hydrogen bonds help to stabilize the mol-ecular structure.
متن کامل2-Benzhydryl-6-tert-butyl-4-methylphenol
The title compound, C(24)H(26)O, was prepared by the reaction between 2-tert-butyl-4-methyl-phenol and diphenyl-methanol in the presence of sulfuric acid. Three benzene rings are attached directly to the central C-H group in a twisted propeller conformation with the local pseudo-C(3) rotational axis coinciding with the C-H bond. There are three short C-H⋯O contacts in the molecule.
متن کامل2,4-Di-tert-butyl-6-[1-(3,5-di-tert-butyl-2-hydroxyphenyl)ethyl]phenyl 4-methylbenzenesulfonate
The title compound, C(37)H(52)O(4)S, was obtained by the reaction of 6,6'-(ethane-1,1-di-yl)bis-(2,4-di-tert-butyl-phenol) and 4-methyl-benzene-1-sulfonyl chloride. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond. Two of the tert-butyl groups are disordered over two sets of sites with occupancies 0.530 (15)/0.470 (15) and 0.615 (11)/0.385 (11).
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810012109